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The preparation of symmetric N-heterocyclic carbenes (NHCs) of the type {(PPh3)2N(CH2)nNPh2} (n=2, 3) is described. NHCs have been used for the complexation of a variety of metal and organic complexes. Moreover, the structurally related alkyne (analogously to carbenes) and oxen are investigated for comparison purposes. It is shown that the NHC is capable of binding strong Lewis acids. NHC coordination also leads to drastic reduction in halogen solubility, and NHC’s can also form strong complexes with organic halides and disulfides as determined by X-ray diffraction, NMR spectroscopy, and a kinetic investigation. NHCs were also found to participate in the copper-catalyzed cross-coupling reaction (Suzuki-Miyaura reaction).A pool table is a table with a top on which balls are arranged into a line or rows, and a cushioned surface below the top upon which a user sits. Games may be played in a traditional manner on a table with a felt or cloth top or, on some tables, on a cushioned playing surface. Other surfaces, such as game table boards, may be used in some games.
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Why is Thomas Becket the only English king authorized to have his own coat of arms?
The coat of arms of the kings of England is unique, representing the three lions of the realm, the cross of St. George and the crown, and all the other elements of England’s royal coat of arms.
Whereas, the coat of arms of
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